The Unmatched Chemical Resistance of FKM: A Comprehensive Guide

Nicolò Sorsoli
March 12, 2025
8 min read

When it comes to sealing solutions in challenging environments, the chemical resistance of FKM (fluoroelastomer) stands out. Known for its exceptional durability against harsh chemicals, FKM is used across numerous industries—including automotive, oil and gas, chemical processing, and pharmaceuticals—where seals are subjected to extreme conditions. In this post, we’ll dive into why FKM is such an effective material, its chemical compatibility, and specific applications that benefit from its unique properties.

What is FKM?

FKM, commonly referred to by the brand name Viton, is a synthetic fluoroelastomer developed for high-performance applications. The material’s strength lies in its unique chemical structure, where fluorine atoms create strong carbon-fluorine bonds. This bond provides FKM with impressive resistance to chemicals, extreme temperatures, and harsh environments that would compromise other elastomers.

The Key to FKM’s Chemical Resistance

The chemical resistance of FKM is due to its high fluorine content. This structure gives FKM the ability to resist degradation and swelling when in contact with various chemical agents. Unlike conventional rubbers, which can deteriorate, swell, or lose integrity when exposed to aggressive substances, FKM remains stable, making it a preferred choice for applications where chemical exposure is unavoidable.

Specific Chemicals That FKM Resists

FKM’s resistance extends to a wide range of chemical agents. Here’s a breakdown of the types of chemicals FKM seals are built to withstand:

  1. Hydrocarbons: FKM excels in applications involving hydrocarbons such as gasoline, diesel, kerosene, and jet fuel. Its resistance to these fuels makes it ideal for the automotive and aerospace industries, where fuel systems and other engine components require long-lasting seals.
  2. Aromatic Compounds: Benzene, toluene, and xylene are just a few examples of aromatic hydrocarbons that can degrade many elastomers. The chemical resistance of FKM ensures that it maintains its integrity in the presence of these aggressive compounds, making it a reliable choice in chemical processing and petrochemical industries.
  3. Organic Solvents: FKM is highly resistant to solvents, including acetone, methyl ethyl ketone (MEK), and other ketones and esters. This resistance is crucial for seals in industries that use strong solvents for cleaning or processing, such as pharmaceuticals and coatings.
  4. Strong Acids: Sulfuric acid, hydrochloric acid, and nitric acid are notorious for their corrosive properties. The chemical resistance of FKM allows it to withstand these strong acids without compromising performance, making it ideal for use in chemical processing plants where acid exposure is common.
  5. Alkalis: FKM also holds up well against basic solutions, including sodium hydroxide and potassium hydroxide. This versatility allows FKM seals to be used in a wide range of environments where both acidic and alkaline agents are present.
  6. Oxidizing Agents: Hydrogen peroxide, ozone, and other oxidizers can degrade most elastomers over time. However, FKM’s stability against oxidizing agents makes it an excellent choice for applications where these chemicals are frequently used, including medical and sanitation equipment.
  7. Chlorinated Solvents: Unlike many elastomers that are vulnerable to chlorinated solvents, FKM seals are resistant to chemicals like trichloroethylene and perchloroethylene. This capability expands FKM’s use in industries that require contact with chlorine or chlorinated substances.

Temperature Stability in Chemical Environments

One of the distinguishing properties of FKM is its ability to maintain performance in both high and low temperatures, even when exposed to chemicals. FKM can withstand temperatures from -20°C up to 200°C (or even 250°C in specialized grades), ensuring that seals do not lose their effectiveness due to thermal stress. This temperature resistance makes FKM ideal for applications like engines, heat exchangers, and chemical reactors, where seals must endure both extreme heat and aggressive chemicals.

Applications Benefiting from the Chemical Resistance of FKM

Thanks to its broad chemical compatibility, FKM is the material of choice for seals in various demanding industries:

  1. Automotive and Aerospace: Fuel systems, turbochargers, and emission controls rely on FKM seals to handle fuels, oils, and high temperatures.
  2. Oil and Gas: FKM seals are crucial for pumps, valves, and other components in refineries and oilfield equipment where exposure to hydrocarbons and chemicals is constant.
  3. Chemical Processing: Seals in reactors, mixers, and storage vessels benefit from FKM’s resistance to acids, alkalis, and solvents.
  4. Pharmaceutical and Food Processing: FKM’s resistance to solvents, oxidizers, and cleaning agents makes it ideal for equipment used in drug manufacturing and food processing.
  5. Industrial Machinery: From hydraulic systems to vacuum pumps, FKM seals are used in machinery requiring durability in chemically aggressive environments.

Advantages of FKM for Chemical Resistance

The chemical resistance of FKM is unparalleled, but the material offers additional benefits:

  1. Long-Term Durability: FKM seals experience less degradation and swelling over time, reducing the need for frequent maintenance and replacement.
  2. Low Permeability: FKM’s low permeability to gases and liquids minimizes leaks, making it ideal for critical applications where containment is essential.
  3. Cost Efficiency: While FKM may have a higher upfront cost than other elastomers, its durability and performance in aggressive environments lead to long-term cost savings.

Conclusion

For industries that require robust sealing solutions in chemically challenging environments, FKM offers a superior choice. The chemical resistance of FKM—coupled with its temperature stability, durability, and compatibility with a range of aggressive agents—makes it the gold standard in sealing solutions. At Siliconiton.it, we are proud to provide high-quality FKM seals tailored to the unique needs of our clients.

To learn more about how our FKM sealing solutions can support your applications, contact us or explore our product offerings at Siliconiton.

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